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When a gas is overvolted at or near atmospheric pressure, it results in a streamer discharge formation. Electrode geometries exert significant impact on the electrical breakdown of gases by altering the spatial profile of the electric field. In many applications the efficient generation of radicals is critical and is determined by the characteristics of the streamer discharge. We examine the effect of electrode geometry on the streamer characteristics and the production of radicals. This is performed for three different electrode geometries: plane–plane, pin–plane, and pin–pin. A two-dimensional rotationally symmetric fluid model is used for the streamer discharge simulation in the hydrogen/air gas mixture. The spatial profile of electron density and the electric field for point electrodes show significant differences when compared to plane electrodes. However, the efficiency of radical generation shows similar trends for the electrode configurations studied. We also present the results of spatial electrical energy density distribution which in turn determines spatial excited species distribution. These results can inform the design of specific applications. 

Size-driven transition of an antiferroelectric into a polar ferroelectric or ferrielectric state is a strongly debated issue from both experimental and theoretical perspectives. While critical thickness limits for such transitions have been explored, a bottom-up approach in the ultrathin limit considering few atomic layers could provide insight into the mechanism of stabilization of the polar phases over the antipolar phase seen in bulk PbZrO3. Here, we use first-principles density functional theory to predict the stability of polar phases in Pt/PbZrO3/Pt nanocapacitors. In a few atomic layer thick slabs of PbZrO3 sandwiched between Pt electrodes, we find that the polar phase originating from the well established R3c phase of bulk PbZrO3 is energetically favorable over the antipolar phase originating from the Pbam phase of bulk PbZrO3. The famous triple-well potential of antiferroelectric PbZrO3 is modified in the nanocapacitor limit in such a way as to swap the positions of the global and local minima, stabilizing the polar phase relative to the antipolar one. The size effect is decomposed into the contributions from dimensionality reduction, surface charge screening, and interfacial relaxation, which reveals that it is the creation of well-compensated interfaces that stabilizes the polar phases over the antipolar ones in nanoscale PbZrO3. 

Abstract This study reports a pulsed laser deposition-assisted synthesis of highly metallic titanium nitride (TiN) and a series of semiconducting titanium oxynitride (TiN_xO_y) compounds in thin film form with tunable plasmonic properties by carefully altering the nitrogen (N)-oxygen (O) ratio. The N/O ratio was controlled from 0.3 (highest oxygen doping of TiN) to ~ 1.0 (no oxygen doping of TiN) by growing the TiN films under nitrogen pressures of 50, 35, and 10 mTorr and high vacuum conditions of 2 × 10⁻⁶ Torr with no external gas introduced. The presence of nitrogen in the deposition chamber during the film growth affects the gas phase oxidation of TiN to TiN_xO_yby increasing the mean free path-dependent N and O inter-collisions per second by two to three orders of magnitudes. The evidence of increased oxidation of TiN to TiN_xO_ywith an increase in nitrogen deposition pressure was obtained using X-ray photoelectron spectroscopy analysis. While the TiN samples deposited in high vacuum conditions had the highest reflectance, TiN_xO_ythin films were also found to possess high reflectance at low frequency with a well-defined edge around 20,000 cm⁻¹. Furthermore, the vacuum-deposited TiN samples showed a large negative dielectric constant of -330 and the largest frequency of zero-crossing at 25,000 cm⁻¹; the TiN_xO_ysamples deposited in the presence of nitrogen ambient also showed promising plasmonic applications at the near-mid infrared range. A comparison of the dielectric constant and loss function data of this research with the literature values for noble metals seems to indicate that TiN and TiN_xO_yhave the potential to replace gold and silver in the visible and near-infrared spectral regions. 

Abstract Autonomous robots are increasingly deployed for long-term information-gathering tasks, which pose two key challenges: planning informative trajectories in environments that evolve across space and time, and ensuring persistent operation under energy constraints. This paper presents a unified framework, , that addresses both challenges through adaptive ergodic search and energy-aware scheduling in multi-robot systems. Our contributions are two-fold: (1) we model real-world variability using stochastic spatiotemporal environments, where the underlying information evolves continuously over space and time under process noise. To guide exploration, we construct a target information spatial distribution (TISD) based on clarity, a metric that captures the decay of information in the absence of observations and highlights regions of high uncertainty; and (2) we introduce ( ), an online scheduling method that enables persistent operation by coordinating rechargeable robots sharing a single mobile charging station. Unlike prior work, our approach avoids reliance on preplanned schedules, static or dedicated charging stations, and simplified robot dynamics. Instead, the scheduler supports general nonlinear models, accounts for uncertainty in the estimated position of the charging station, and handles central node failures. The proposed framework is validated through real-world hardware experiments, and feasibility guarantees are provided under specific assumptions.[Code: https://github.com/kalebbennaveed/mEclares-main.git][Experiment Video: https://www.youtube.com/watch?v=dmaZDvxJgF8]